Calibration and Validation of an Autonomous, Novel, Low-Cost, Dynamic Flux Chamber for Measuring Landfill Methane Emissions.
Journal Article
Overview
abstract
A low-cost, dynamic flux chamber optimized for landfill emissions measurement was designed, fabricated, calibrated, and validated for measurements of methane flux ranging from 0 to 150 g/m2-day. A centrifugal blower fan and a flow meter were plumbed in series to draw a bypass flow through the flux chamber. Both ambient and chamber methane concentrations were measured using the arrays of four low-cost metal oxide sensors. Leveraging the sensors' overlapping sensitivity to changes in methane concentration, temperature, and humidity, multiple linear regressions were trained on laboratory data and combined into a piecewise methane calibration function. An algorithm was developed to select the most useful interaction terms among all sensor responses to optimize the predictors in each model. The piecewise regions for methane measurement were 0-100 ppm, 100-1500 ppm, and 1500-12,000 ppm. The root mean squared errors for each piecewise region were 3.1 ppm, 21 ppm, and 307 ppm, respectively. Controlled quantities of methane were delivered to the flux chamber in a laboratory setting for validation. Measurements yielded good agreement with an RMSE and MBE of 7.3 g m-2 d-1 and 2.2 g m-2 d-1, respectively. The flux chamber was tested at a closed landfill to validate its ability to autonomously and continuously operate in the field.
